Show this to your docter SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - - NAME: 1,4-PHENYLENEDIAMINE SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - - CAS #: 106-50-3 EC NO: 203-404-7 SYNONYMS P-AMINOANILINE * 4-AMINOANILINE * BASF URSOL D * P-BENZENEDIAMINE * 1, 4-BENZENEDIAMINE * BENZOFUR D * C.I. 76060 * C.I. DEVELOPER 13 * C.I. OXIDATION BASE 10 * DEVELOPER 13 * DEVELOPER PF * P-DIAMINOBENZENE * 1,4-DIAMINOBENZENE * DURAFUR BLACK R * P-FENYLENDIAMIN (CZECH) * FENYLENODWUAMINA (POLISH) * FOURAMINE D * FOURRINE D * FOURRINE 1 * FUR BLACK 41867 * FUR BROWN 41866 * FURRO D * FUR YELLOW * FUTRAMINE D * NAKO H * ORSIN * OXIDATION BASE 10 * PARA * PARAPHENYLEN-DIAMINE * PELAGOL D * PELAGOL DR * PELAGOL GREY D * PELTOL D * 1,4- PHENYLENEDIAMINE * P-PHENYLENEDIAMINE (ACGIH:DOT:OSHA) * PPD * RENAL PF * RODOL D * SANTOFLEX IC * TERTRAL D * UN1673 (DOT) * URSOL D * USAF EK-394 * VULKANOX 4020 * ZOBA BLACK D * SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - - LABEL PRECAUTIONARY STATEMENTS TOXIC TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. POSSIBLE RISK OF IRREVERSIBLE EFFECTS. POSSIBLE MUTAGEN. TARGET ORGAN(S): LIVER, KIDNEYS IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - - IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE. SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - - EXTINGUISHING MEDIA WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. SPECIAL FIREFIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. UNUSUAL FIRE AND EXPLOSIONS HAZARDS EMITS TOXIC FUMES UNDER FIRE CONDITIONS. SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - - EVACUATE AREA. WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - - REFER TO SECTION 8. SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - - WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. USE ONLY IN A CHEMICAL FUME HOOD. DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. TOXIC. IRRITANT. SENSITIZER. POSSIBLE MUTAGEN. KEEP CONTAINER CLOSED. STORE IN A COOL DRY PLACE. SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - - APPEARANCE AND ODOR TAN-BROWN FLAKES PHYSICAL PROPERTIES BOILING POINT: 267 C MELTING POINT: 143 C TO 145 C FLASHPOINT >230 109C VAPOR PRESSURE: 1.08MM 100 C VAPOR DENSITY: 3.7 SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - - INCOMPATIBILITIES ACIDS ACID CHLORIDES ACID ANHYDRIDES CHLOROFORMATES STRONG OXIDIZING AGENTS MAY DARKEN ON STORAGE HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE NITROGEN OXIDES SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - - ACUTE EFFECTS HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. ABSORPTION INTO THE BODY LEADS TO THE FORMATION OF METHEMOGLOBIN WHICH IN SUFFICIENT CONCENTRATION CAUSES CYANOSIS. ONSET MAY BE DELAYED 2 TO 4 HOURS OR LONGER. MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS. CHRONIC EFFECTS LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. TARGET ORGAN(S): LIVER, KIDNEYS RTECS #: SS8050000 P-PHENYLENEDIAMINE IRRITATION DATA SKN-HMN 250 MG/24H MLD JSCCA5 23,371,72 SKN-MUS 250 MG/24H MLD JSCCA5 23,371,72 SKN-DOG 250 MG/24H MLD JSCCA5 23,371,72 SKN-RBT 12500 UG/24H MLD FCTXAV 15,607,77 SKN-RBT 250 MG/24H MOD JSCCA5 23,371,72 SKN-PIG 250 MG/24H MLD JSCCA5 23,371,72 SKN-GPG 250 MG/24H MLD JSCCA5 23,371,72 TOXICITY DATA ORL-RAT LD50:80 MG/KG JTEHD6 2,657,77 IPR-RAT LD50:37 MG/KG JTEHD6 2,657,77 UNR-RAT LD50:133 MG/KG GTPZAB 31(8),46,87 IPR-MUS LD50:50 MG/KG NTIS** AD277-689 UNR-MUS LD50:331 MG/KG GISAAA 50(6),78,85 ORL-GPG LD50:145 MG/KG GISAAA 53(7),62,88 UNR-GPG LD50:145 MG/KG GTPZAB 31(8),46,87 ORL-QAL LD50:100 MG/KG AECTCV 12,355,83 ORL-BWD LD50:100 MG/KG AECTCV 12,355,83 TARGET ORGAN DATA BRAIN AND COVERINGS (OTHER DEGENERATIVE CHANGES) BEHAVIORAL (MUSCLE WEAKNESS) BEHAVIORAL (COMA) CARDIAC (PULSE RATE INCREASED WITHOUT FALL IN BP) LUNGS, THORAX OR RESPIRATION (ACUTE PULMONARY EDEMA) LUNGS, THORAX OR RESPIRATION (DYSPNAE) LUNGS, THORAX OR RESPIRATION (RESPIRATORY STIMULATION) LUNGS, THORAX OR RESPIRATION (OTHER CHANGES) GASTROINTESTINAL (CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS) GASTROINTESTINAL (NAUSEA OR VOMITING) NUTRITIONAL AND GROSS METABOLIC (BODY TEMPERATURE DECREASE) ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - - DATA NOT YET AVAILABLE. SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - - DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - - CONTACT THE MANUFACTURER FOR TRANSPORTATION INFORMATION. SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - - EUROPEAN INFORMATION TOXIC R 23/24/25 TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. R 40 POSSIBLE RISK OF IRREVERSIBLE EFFECTS. R 43 MAY CAUSE SENSITIZATION BY SKIN CONTACT. S 28 AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER. S 45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). REVIEWS, STANDARDS, AND REGULATIONS OEL=MAK ACGIH TLV-TWA 0.1 MG/M3 85INA8 6,1222,91 IARC CANCER REVIEW:ANIMAL INADEQUATE EVIDENCE IMEMDT 16,125,78 IARC CANCER REVIEW:HUMAN NO ADEQUATE DATA IMEMDT 16,125,78 IARC CANCER REVIEW:GROUP 3 IMSUDL 7,56,87 MSHA STANDARD-AIR:TWA 0.1 MG/M3 (SKIN) DTLVS* 3,205,71 OSHA PEL (GEN INDU):8H TWA 0.1 MG/M3 (SKIN) CFRGBR 29,1910.1000,94 OSHA PEL (CONSTRUC):8H TWA 0.1 MG/M3 (SKIN) CFRGBR 29,1926.55,94 OSHA PEL (SHIPYARD):8H TWA 0.1 MG/M3 (SKIN) CFRGBR 29,1915.1000,93 OSHA PEL (FED CONT):8H TWA 0.1 MG/M3 (SKIN) CFRGBR 41,50-204.50,94 OEL-AUSTRALIA:TWA 0.1 MG/M3;SKIN JAN93 OEL-BELGIUM:TWA 0.1 MG/M3;SKIN JAN93 OEL-DENMARK:TWA 0.1 MG/M3;SKIN JAN93 OEL-FINLAND:TWA 0.1 MG/M3;STEL 0.3 MG/M3;SKIN JAN93 OEL-FRANCE:TWA 0.1 MG/M3;SKIN JAN93 OEL-GERMANY:TWA 0.1 MG/M3;SKIN JAN93 OEL-THE NETHERLANDS:TWA 0.1 MG/M3;SKIN JAN93 OEL-THE PHILIPPINES:TWA 0.1 MG/M3;SKIN JAN93 OEL-POLAND:TWA 0.1 MG/M3 JAN93 OEL-RUSSIA:STEL 0.05 MG/M3 JAN93 OEL-SWEDEN:TWA 0.1 MG/M3;STEL 0.3 MG/M3;SKIN JAN93 OEL-SWITZERLAND:TWA 0.1 MG/M3;STEL 0.2 MG/M3;SKIN JAN93 OEL-UNITED KINGDOM:TWA 0.1 MG/M3;SKIN JAN93 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV NIOSH REL TO P-PHENYLENE DIAMINE-AIR:10H TWA 0.1 MG/M3 (SK) NIOSH* DHHS #92-100,92 NOHS 1974: HZD 56950; NIS 9; TNF 2017; NOS 11; TNE 14983 NOES 1983: HZD 56950; NIS 6; TNF 5390; NOS 7; TNE 49939; TFE 37209 EPA GENETOX PROGRAM 1988, POSITIVE: CELL TRANSFORM.-RLV F344 RAT EMBRYO EPA GENETOX PROGRAM 1988, POSITIVE: CELL TRANSFORM.-SA7/SHE; D MELANOGASTER SEX-LINKED LETHAL EPA GENETOX PROGRAM 1988, NEGATIVE: CARCINOGENICITY-MOUSE/RAT; RODENT DOMINANT LETHAL EPA GENETOX PROGRAM 1988, NEGATIVE: N CRASSA-ANEUPLOIDY; SPERM MORPHOLOGY-MOUSE EPA GENETOX PROGRAM 1988, INCONCLUSIVE: MAMMALIAN MICRONUCLEUS EPA TSCA SECTION 8(B) CHEMICAL INVENTORY EPA TSCA 8(A) PRELIMINARY ASSESSMENT INFORMATION, FINAL RULE FEREAC 47,26992,82 EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, OCTOBER 1995 U.S. INFORMATION THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - - THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. THE MANUFACTURER SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING